黄辉

Hello.

Welcome visiting my research group! 

承担《材料现代测试方法》本科生、《电化学原理与方法》研究生课程教学任务， 

国家基金

1. 硫基高性能固态锂电池的体系设计和界面调控，国家自然科学基金面上项目—联合重点项目子课题，2021-2024，负责人。

2. TiO_2-xN_x/Ni(OH)₂纳米复合薄膜的制备及可光充电特性，国家自然科学基金面上项目，2007-2009，负责人。

3. 定向CNTs/MTiO₃(M=Sr,Ba,Ca,La)复合电极的制备及光充电嵌锂特性，国家自然科学基金青年基金项目，2005，负责人。

浙江省自然科学基金

1. 熔盐电解还原CO₂制备储能碳纳米材料微结构调控及形成机理，浙江省自然科学基金，2018-2020，负责人。

2. 石墨电解法制备石墨烯反应新体系及形成机理研究，浙江省自然科学基金，2013-2015，负责人。

3. 核壳结构氧化锌/导电陶瓷复合材料在循环充放电过程中的微观形态衍变及电化学性能，浙江省自然科学基金，2010-2011，负责人。

           3. 表面修饰纳米SrTiO₃贮氢合金电极的光充电贮氢特性，浙江省自然科学基金，2005-2007，负责人。

浙江省科技计划项目

1. 先进储能关键技术与装备研制-高效储能用高能量密度锂硫电池及关键技术研究，浙江省重点研发项目，2016-2018。

2.基于硅碳负极的高比能和高安全锂离子电池，浙江省尖兵领雁研发攻关计划项目，2023-2025。

重大企业合作项目：

1. 面向实用碳包覆氧化亚硅复合材料结构设计及优化，天能集团合作项目，2023-2025，项目负责人

2.新型高容量核壳结构锂离子电池正极材料，美国福特汽车公司合作项目，2016-2018，项目负责人。

2. 高镍正极表面稳定化和电池应用工艺，浙江美都海创锂电科技有限公司，2018-2022，项目负责人。

近期第一作者或通讯作者发表的论文：（2021.1.1~）

1. Xiang Yan; Liuyi Hu; Yuanchun Zhang; Fei He*; Tianqi Yang; Tiansheng Chen; Yang Xia; Xinhui Xia*; Jun Zhang; Yongping Gan; Wenkui Zhang; Xinping He; Ruyi Fang; Xinyong Tao; Hui Huang*; LiF/LiBO2-Rich Silicon-Based Anode Enabling Stable Operation of Sulfide All-Solid-State Lithium Ion Batteries without Extra External Pressure, Nano Letters, 2026, 26(1): 458-466

2. Xiang Yan; Tiansheng Chen; Tengtao Hu; Yang Xia*; Jun Zhang; Xinping He; Xinhui Xia; Ruyi Fang; Yongping Gan; Min Fan; Wenkui Zhang; Xinyong Tao; Hui Huang*; Enabling a Stable and Kinetically Enhanced Interface for Silicon Anodes via in Situ Formation of F/P‐Doped LixSiyOz and Carbon Composites, Small, 2026: e13563

3. Tiansheng Chen, Xiang Yan*, Tengtao Hu, Jun Zhang, Huaizheng Huang, Yang Xia, Wenkui Zhang , Xinhui Xia, Xinyong Tao, Xue Li*, and Hui Huang*，Dual-Armor Architecture-Mediated Microstructural Engineering of Germanium Anode for Advanced Liquid- and Solid-State Batteries，Energy Environ. Mater. 2026, 0, e70308

4. Liuyi Hu, Fei He*, Xiang Yan, Xiaohua Shen, Yang Xia, Jun Zhang, Xinhui Xia,Wenkui Zhang, Xinyong Tao*, Xidong Duan*, Hui Huang*，Bidirectional inhibition of polysulfide shuttle and dendrite growth via a trimetallic MOF-based separator，Chemical Engineering Journal 531 (2026) 173770

5. Fei Qian, Liuyi Hu, Yonggen Jin, Linhe Li, Ruyi Fang, Jun Zhang, Xinping He, Yongping Gan*, Yang Xia, Xinhui Xia, Wenkui Zhang, Hui Huang*,In-situ construction of Fe nanoparticles modified host materials for all-solid-state lithium-sulfur batteries with enhanced kinetic performance,Electrochimica Acta 524 (2025) 146051

6. Binyu Lu, Liuyi Hu, Xiang Yan, Yang Xia, Xinping He, Jun Zhang, Ruyi Fang,Wenkui Zhang*, Yongping Gan, Min Fan, Xinhui Xia, Hui Huang*,In-situ constructed copper nanoparticles facilitates polysulfide adsorption and catalytic conversion in high-performance lithium-sulfur batteries,Electrochimica Acta 537 (2025) 146877

7. Jiaqi Jin, Liuyi Hu, Tengtao Hu, Xinping He, Yang Xia,* Jun Zhang, Yongping Gan, Ruyi Fang, Xinhui Xia, Wenkui Zhang, and Hui Huang*，MXene-Induced 2D Hard Carbon with In Situ Embedding ofT iC Scaffolds Enabling Fast Na+ Diffusion and Interfacial Stabilization, Small, 2025,2412196

8. Jingfeng Cao, Xiang Yan, Dan Li, Liuyi Hu, Tiansheng Chen, Weiwei Gao,Wenlong Song, Xinhui Xia, Yang Xia, Wenkui Zhang, Hui Huang,*In situ constructiion of ion/electron conductive components via lithiation strategy enhancing cycling capability and initial Coulombic efficiency of Si anode, Chemical Engineering Journal 504 (2025) 159049

9. Tiansheng Chen, Xiang Yan, Yuanchun Zhang, Jingfeng Cao, Liuyi Hu, Weiwei Gao,  Dan Li, Wenlong Song, Jun Zhang, Yang Xia, Xinhui Xia, Wenkui Zhang, Hui Huang*, An effective strategy for regulating SiOx/Si components by thermal reduction of biomass diatomite for lithium-ion battery anodes, Journal of Energy Storage 138 (2025) 118704

10. Liuyi Hu, Tianqi Yang, Xiang Yan, Yaning Liu, Wenkui Zhang,* Jun Zhang, Yang Xia, Yao Wang, Yongping Gan, Xinping He, Xinhui Xia, Ruyi Fang, Xinyong Tao, and Hui Huang*，In Situ Construction of LiF−Li3N-Rich Interface Contributed to Fast Ion Diffusion in All-Solid-State Lithium−Sulfur Batteries, ACS Nano 2024, 18, 8463−8474,

11. Liuyi Hu, Tianqi Yang, Luoting Zhou, Xiang Yan, Yaning Liu, Yang Xia, Wenkui Zhang,* Jun Zhang, Yongping Gan, Xinping He, Xinhui Xia, Ruyi Fang, Xinyong Tao, and Hui Huang*，In Situ Polymerization Bi-Functional Gel Polymer Electrolyte for High Performance Quasi-Solid-State Lithium−Sulfur Batteries, Small 2024, 2402862.

12. Chunbo Yang, Xiang Yan, Weiwei Gao, Yang Xia, Hongjie Liu, Liuyi Hu, Wenlong Song, Wenkui Zhang,

Xinhui Xia and Hui Huang*,Facile Synthesis of Laminated Si@C-Fe3O4 Composite from Exfoliation of Zintl Phase: A Promising Lithium Battery Anode with Superior Rate Capability and Cycling Stability, ACS Applied  Energy Materials  2024, 7, 1313-1319.

13. Binyu Lu, Liuyi Hu, Wenkui Zhang,* Jun Zhang, Yang Xia, Yongping Gan, Xinping He, Xinhui Xia,Ruyi Fang, and Hui Huang*,Li-Ga Alloy-Contained Hybrid Solid Electrolyte Interphase Induced by In Situ Polymerization for High-Performance Lithium Metal Batteries, ACS Applied Materials Interfaces, 2024, 16. 55314-55324.

14. Xiang Yan, Liuyi Hu, Yang Xia, Jun Zhang, Wenkui Zhang,* Yongping Gan, Xinping He, Xinhui Xia, and Hui Huang*, Carbon Nanofiber Cages and Interface Engineering Stabilizing Silicon-Based Anode for High-Performance Lithium-Ion Batteries, ACS Applied Energy Materials, 2023, 7, 403-413.

15. Liuyi Hu, Zhihang Lu, Fei Chen, Jun Zhang, Yang Xia, Wenkui Zhang,* Yongping Gan, Xinping He, Wenlong Song, and Hui Huang*, Supercritical-Assisted Ball-Milling Synthesis of Multicomponent Si/Fe3O4/C Composites for Outstanding Lithium-Storage Capability, Energy and Fuels, 2023,37, 8042-8050.

16. Xiang Yan,† Zefeng Fu,† Luoting Zhou, Liuyi Hu, Yang Xia, Wenkui Zhang,* Yongping Gan, Jun Zhang, Xinping He, and Hui Huang*,New Chemical Synthesis Strategy To Construct a Silicon/Carbon Nanotubes/Carbon-Integrated Composite with Outstanding Lithium Storage Capability, ACS Applied Materials Interfaces, 2023,15, 17986-17993.

17. Liuyi Hu, Xiang Yan, Tianqi Yang, Jun Zhang, Yang Xia, Wenkui Zhang * , Yongping Gan,  Xinping He, Xinhui Xia, Hui Huang *,Enhanced the interfacial compatibility by lithium anode of DOL-based in-situ polymerized gel polymer electrolytes with addition of silicon nanoparticles. Journal of Energy Storage, 2023, 66, 107368.

18. Yuxuan Zheng, Junkai Ma, Xinping He, Yongping Gan, Jun Zhang, Yang Xia, Wenkui Zhang, Hui Huang*, Fe₃O₄ Contribution to Core-Shell Structured Si@C Nanospheres as High-Performance Anodes for Lithium-Ion Batteries, Journal of Electronic Materials, 2023, 52, 1730-1739.

19. Xiang Yan, Liuyi Hu, Xinping He, Jun Zhang, Wenkui Zhang,* Yongping Gan, Yang Xia,

and Hui Huang*,Ball-Milling-Triggered Synthesis of Si/C/SiC@MCMB Composites from Carbon Dioxide for Improved Lithium Storage Capability, Energy and Fuels, 2023, 37, 746-753.

20. Liuyi Hu, Xiang Yan, Zefeng Fu, Jun Zhang, Yang Xia, Wenkui Zhang,* Yongping Gan, Xinping He, and Hui Huang*, A “Reinforced Concrete” Structure of Silicon Embedded into an In Situ Grown Carbon Nanotube Scaffold as a High-Performance Anode for Sulfide-Based All-Solid-State Batteries, ACS Applied Energy Materials, 2022, 5, 14353-14360.

21. Junkai Ma,Yuxuan Zheng,Yongping Gan,Jun Zhang,Yang Xia, Xinping He,Wenkui Zhang,Hui Huang*,Improved Lithium Storage Capability of Si Anode by Ball-Milling Produced Graphitic Carbon Sheet and Fe₃O₄ Nanoparticles, Journal of Electronic Materials, 2022, 51, 4780–4789. 

22. Jiage Yua,Kun Wang,Wenlong Song,Hui Huang⁎, Chu Liang,Yang Xia,Jun Zhang,Yongping Gan,Feng Wang,Wenkui Zhanga⁎,A low temperature MgH₂-AlCl₃-SiO₂ system to synthesize nano-silicon for high-performance Li-ion batteries, Chemical Engineering Journal, 2021,406, 126805.

23. Zefeng Fu, Feixiang Bian, Junkai Ma, Wenkui Zhang,* Yongping Gan, Yang Xia, Jun Zhang, Xinping He, and Hui Huang*, In Situ Synthesis of a Si/CNTs/C Composite by Directly Reacting Magnesium Silicide with Lithium Carbonate for Enhanced Lithium Storage Capability, Energy and Fuels, 2021, 35, 24, 20386–20393.

24. Hui Huang, Gangfeng Yang, Jiage Yu, Jun Zhang , Yang Xia, Kun Wang , Chu Liang , Yongping Gan∗ , Xinping He, Wenkui Zhang∗,One-pot synthesis of nanocrystalline SnS@tremella-like porous carbon by supercritical CO₂ method for excellent sodium storage performance, Electrochimica Acta, 2021,373,137933.

2021年之前发表的代表性论文（第一或通讯作者）

[1] Jiage Yu, Kun Wang, Wenglong Song, Hui Huang*, Chu Liang, Yang Xia, Jun Zhang, Yongping Gan, Fang Wang, Wenkui Zhang*, A low temperature MgH₂-AlCl₃-SiO₂ system to synthesize nano-silicon for high-performance Li-ion batteries, Chemical Engineering Journal, 2021,406, 126805

[2] Qiu yang, Huang Hui*, Song Wenlong, Gan Yongping, Wang Kun, Zhang Jun, Xia Yang, Liang Chu, Zhang Wenkui*. In-situ electrolytic synthesis and superior lithium storage capability of Ni–NiO/C nanocomposite by sacrificial nickel anode in molten carbonates. Journal of Alloys and Compounds, 2020, 834, 155111.

[3] Huang Hui, Qiu Yang, Liang Chu, Zhang Jun, Gan yongping, Xia Yang, He Xinping, Zhang Wenkui*. Tremella-like porous carbon derived from one-step electroreduction of molten carbonates with superior rate capability for sodium-ion batteries. Ionics, 2018, 24: 2233-2239.

[4] Bian Feixiang, Yu Jiage, Song Wenlong, Huang Hui*, Liang Chu, Gan Yongping, Xia Yang, Zhang Jun, He Xinping, Zhang Wenkui*. A new magnesium hydride route to synthesize morphology-controlled Si/rGO nanocomposite towards high-performance lithium storage. Electrochimica Acta, 2020, 330: 135248.

[5] Shi Cheng, Huang Hui*, Xia Yang, Yu Jiage, Fang Ruyi, Liang Chu, Zhang Jun, Gan Yongping, Zhang Wenkui*. Importing tin nanoparticles into biomass-derived silicon oxycarbides with high-rate cycling capability based on supercritical fluid technology. Chemistry-A European Journal, 2019, 25:7719-7725.

[6] Huang Hui, Shi Cheng, Fang Ruyi, Xia Yang, Liang Chu, Gan Yongping, Zhang Jun, Wenkui Zhang*, Bio-templated fabrication of MnO nanoparticles in SiOC matrix with lithium storage properties, Chemical Engineering Journal, 2019, 359: 584-593.

[7] Yu Li, Huang Hui*, Jiage Yu, Yang Xia, Chu Liang, Yongping Gan, Jun Zhang, Wenkui Zhang*, Improved high rate capability of Li[Li_0.2Mn_0.534Co_0.133Ni_0.133]O₂ cathode material by surface modification with Co₃O₄, Journal of Alloys and Compounds, 2019, 783: 349-356.

[8] Jiage Yu, Huang Hui*, Feixiang Bian, Chu Liang, Yang Xia, Jun Zhang, Yongping Gan, and Wenkui Zhang, Supercritical CO₂-fluid-assisted synthesis of TiO₂  quantum dots/reduced graphene oxide composites for outstanding sodium storage capability, ACS Applied Energy Materials, 2018, 1: 7213-7219.

[9] Yu jiage, Huang Hui*, Gan Yongping, Xia Yang, Liang Chu, Zhang Jun, Tao Xinyong, Wenkui Zhang, A new strategy for the construction of 3D TiO₂ nanowires/reduced graphene oxide for high-performance lithium/sodium batteries, Journal of Materials Chemistry A, 2018, 6: 24256- 24266.

[10] Huang Hui, Cheng Cheng, Liang Sheng, Liang Chu*, Xia Yang, Gan Yongping, Zhang Jun, Tao Xinyong, Zhang Wenkui*, Toast-like porous carbon derived from one-step reduction of CaCO₃ for electrochemical lithium storage, Carbon, 2018, 130, 559-565.

[11] Liang Chu, Liang Sheng, Xia Yang, Chen Yun, Huang Hui*, Gang Yongping, Tao Xingyon, Zhang Jun, Zhang wenkui*, H₂O-induced self-propagating synthesis of hierarchical porous carbon: a promising lithium storage material with superior rate capability and ultra-long cycling life, Journal of Materials Chemistry A, 2017, 5, 18221-18229.

[12] Huang Hui, Yu Jiage, GanYongping, Xia Yang, Liang Chu, Zhang Jun, Tao Xingyon, Zhang Wenkui*, Hybrid nanoarchitecture of TiO₂ nanotubes and graphene sheet for advanced lithium ion batteries, Materials Research Bulletin, 2017,96, 425-430.

[13] Huang Hui, Shen Yong, Xia Yang, Liang Chu, Gan Yongping, Tao Xingyon, Zhang Jun, Zhang Wenkui*, C-S hybrids prepared by electrodeposition and thermal diffusion methods from kapok- based amorphous carbon flake as the cathode materials of Li-S batteries, New Carbon Materials, 2017,32, 427-433.

[14] Huang Hui, Liu Junjie, Xia Yang, Cheng Cheng, Liang Chu, Gan Yongping, Zhang Jun, Tao Xinyong, Zhang Wenkui*, Supercritical fluid assisted synthesis of titanium carbide particles embedded in mesoporous carbon for advanced Li-S batteries, Journal of alloys and Compounds, 2017, 706, 227-233.

[15] Zhang Liyuan, Huang Hui*, Xia Yang, Liang Chu, Zhang WenKui*, Luo Jianming, Gan Yongpin, Zhang Jun, Tao Xingyon, Fan Hongjin, High-content of sulfur uniformly embedded in mesoporous carbon: a new electrodeposition synthesis and an outstanding lithium-sulfur battery cathode, Journal of Materials Chemistry A, 2017,5, 5905-5911.

[16] Huang Hui, Feng Tong, Gan Yongping, Fang Mingyu, Xia Yang, Liang Chu, Tao Xinyong, Zhang Wenkui*, TiC/NiO core/shell nanoarchitecture with battery-capacitive synchronous lithium storage for high-performance lithium-ion battery, ACS Applied Materials & Interfaces, 2015, 7, 11842-11848.

[17] Zhu Wenjun, Huang, Hui*, Zhang Wenkui, Tao Xinyong, Gan Yongping, Xia Yang, Yang Hui, Guo Xingzhong, Synthesis of MnO/C composites derived from pollen template for advanced lithium-ion batteries, Electrochimica Acta, 2015, 152: 286-293.

[18] Zhang Liyuan, Huang Hui*, Yin Hailin, Xia Yang, Luo Jianmin, Liang Chu, Gan Yongping, Tao Xinyong, Zhang Wenkui, Sulfur synchronously electrodeposited onto exfoliated graphene sheets as a cathode material for advanced lithium-sulfur batteries, Journal of Materials Chemistry A, 2015, 3, 16513-16519.

[19] Huang Hui, Zhang Liyuan, Xia Yang, Gan Yongping, Tao Xinyong, Liang Chu, Zhang Wenkui, Well-dispersed ultrafine Mn₃O₄ nanocrystals on reduced graphene oxide with high electrochemical Li-storage performance, New Journal of Chemistry , 2014. 38, 4743-4747.

[20] Zhu Wenjun; Huang Hui*; Gan Yongping; Tao Xinyong; Xia Yang; Zhang Wenkui, Mesoporous cobalt monoxide nanorods grown on reduced graphene oxide nanosheets with high lithium storage performance, Electrochimica Acta, 2014, 138, 376-382.

[21] Zhen Qiu, Hui Huang*,Jun Du, Xinyong Tao, Yang Xia, Tong Feng, Yongping Gan, Wenkui Zhang, Biotemplated synthesis of bark-structured TiC nanowires as Pt catalyst support with enhanced electrocatalytic activity and durability for methanol oxidation. Journal of Materials Chemistry A, 2014.

[22] Hui Huang, Zhaoyang Yu, Wenjun Zhu, Yongping Gan, Yang Xia, Xinyong Tao, Wenkui Zhang*, Hierarchically porous nanoflowers from TiO₂-B nanosheets with ultrahigh surface area for advanced lithium-ion batteries, Journal of Physics and Chemistry of Solids, 2014, 75, 619-623.

[23] Zhen Qiu, Hui Huang*, Jun Du, Tong Fen, Wenkui Zhang, Yongping Gan, Xinyong Tao, NbC nanowire-supported Pt nanoparticles as a high performance catalyst for methanol electro- oxidation, Journal Physical Chemistry C, 2013, 117, 13770-13775.

[24] Hui Huang, Junwu Fang, Yang Xia, Xinyong Tao, Yongping Gan, Jun Du, Wenjun Zhu, Wenkui Zhang*, Construction of sheet/belt hybrid nanostructures by one-dimensional mesoporous TiO₂(B) nanobelts and graphene sheets for advanced lithium-ion batteries Journal of Materials Chemistry A, 2013, 1, 2495-2500.

[25] Hui Huang*, Yang Xia, Xinyong Tao, Jun Du, Junwu Fang, Yongping Gan, Wenkui Zhang*, Highly efficient electrolytic exfoliation of graphite into graphene sheets based on Li ions intercalation-expansion-microexplosion mechanism. Journal of Materials Chemistry, 2012, 22, 10452-10456.

[26] Hui Huang, Wenjun Zhu, Xinyong Tao, Yang Xia, Zhaoyang Yu, Junwu Fang, Yongping Gan, Wenkui Zhang*, Nanocrystal-constructed mesoporous single-crystalline Co₃O₄ nanobelts with superior rate capability for advanced lithium-ion batteries. ACS Applied Materials & Interfaces 2012, 4, 5974−5980.

[27] Hui Huang, Hongfeng Chen, Yang Xia, Xinyong Tao, Yongping Gan, Xianxian Weng, Wenkui Zhang*, Controllable synthesis and visible-light-responsive photocatalytic activity of Bi₂WO₆ fluffy microsphere with hierarchical architecture. Journal of Colloid and Interface Science 2012, 370, 132-138. 

授权发明专利（2020.1.1~至今）

1. 一种碳化硅粉体的制备方法，ZL 2022100318682, 2023.05.26。

2. 一种制备非晶硅/碳复合材料的方法，ZL2019107916115, 2023.03.14。

3. 一种利用超临界CO₂流体介质制备Si/Fe/Fe₃O₄/C复合材料的方法，ZL2021109808131, 2023.03.14。

4. 一种原位碳包覆制备核壳型硅/碳复合材料的方法及其应用，ZL2019105934833，2021.10.15。

5. 一种低温制备硅/碳化硅材料的方法，ZL 2019107916064，2021.10.15。

6. 一种超临界二氧化碳流体制备二氧化硅/石墨烯复合材料的方法及应用，ZL2017114981321，2021.03.23

7. 一种超临界二氧化碳流体制备二氧化钛/石墨烯复合材料的方法及应用，ZL2017114978386，2021.03.02

8. 一种Ni-NiO/C复合材料的制备方法及应用，ZL2019100131119，2020.12.15

1、2018年浙江省自然科学二等奖，张文魁、陶新永、黄辉、夏阳、甘永平。

2、浙江工业大学第四届研究生“我心目中的好导师”，2013年

3、浙江工业大学优秀共产党员，2014年