-
个人简介
李郁锦，副教授，博士
联系方式：13634100950，Email: lyjzjut@zjut.edu.cn
主要研究方向：
绿色合成；荧光分子的设计与合成；杂环化学
主要从事功能色素分子设计合成及性能研究，杂环化合物的合成方法及绿色合成及工艺的研究开发；已主持国家自然科学基金1项、浙江省自然科学基金各2项，主持企业横向项目4项。已在Org. Lett、Adv. Synth. Catal.、J. Org. Chem.、Dyes and Pigment、Tetrahedron等刊物上发表SCI论文40余篇，其中SCI论文30篇。申请专利6项，授权发明专利 4项。
1995年9月--1999年7月 兰州大学 有机化学专业 学士学位
1999年9月--2004年7月 兰州大学 有机化学专业 博士学位2004年7月---2006年9月 上海有机所有机合成 博士后
2006年11月---- 浙江工业大学化学工程学院 副教授主要科研成果：
1. Li, Yujin; Xu, Hui; Xing, Mengming;Huang, Fang; Jia, Jianhong; Gao, JianrongIodine-Promoted Construction of Polysubstituted 2,3-Dihydropyrroles from Chalcones and beta-Enamine Ketones (Esters)Org. Lett17(15),3690,2015,
2. Zheng, Jie; Huang, Fang;Li, Yujin; Xu, Tianwei; Xu, Hui;Jia, Jianhong; Ye, Qing; Gao, JianrongThe aggregation-induced emission enhancement properties of BF2 complex isatin-phenylhydrazone: Synthesis and fluorescence characteristicsDyesand Pigments113, 502-509, 2015
3. Yu-Jin Li,* Huan-Ming Huang, Qing Ye, Li-Fen Hou, Wu-Bin Yu,Jian-Hong Jia, and JianRong Gao, * The Construction of Polysubstituted Aromatic Core Derivatives via a Cycloaddition/Oxidative Aromatization Sequnce from Quinone and b-Enamino Esters Adv. Synth. Catal., 356, 421 – 427, 2014
4. Huan-Ming Huang, Yu-Jin Li,* Qing Ye, Wu-Bin Yu, Liang Han, Jian-Hong Jia, and Jian-Rong Gao* Iodine-Catalyzed 1,3-Dipolar Cycloaddition/Oxidation/ Aromatization Cascade with Hydrogen Peroxide as the Terminal Oxidant: GeneralRoute to Pyrrolo[2,1-a]isoquinolinesJ. Org. Chem., 79 (3), 1084–1092, 2014
5. Yu-Jin Li,* Huan-Ming Huang, Hua-Qing Dong, Jian-Hong Jia, Liang Han, Qing Ye, and Jian-Rong Gao* The Synthesis of Benzo[f]isoindole-1,3-dicarboxylates via an I2-Induced 1,3-Dipolar Cycloaddition ReactionJ. Org. Chem., 78 (18), 9424– 9430, 2013
6. Huan-ming Huang, Yu-jin Li *, Jian-rong Yang, Jian-hong Jia, Qing Ye, Liang Han, Jianrong Gao * Efficient access to naphthoquinon-1,3-dithioles: formal cycloaddition and oxidation of quinones and amines with CS2 Tetrahedron, 69, 5221-5226, 2013
7. Huanming Huang, Jing Han, Fang Xu, Yujin Li,* Huaqing Dong, Wubin Yu, and Jianrong Gao* Facile One-pot Synthesis of Naphthoquinone1,3-Dithioles via 2,3- Dichlor-1,4-naphthoquinone and Amines Involving CS2 Chem. Lett.,42,921-923,2013
8. Huan-ming Huang, Jian-rong Gao, Li-fen Hou, Jian-hong Jia, Liang Han, Qing Ye and Yu-jin Li* The first iodine improved 1,3-dipolar cycloaddition: facile and novelsynthesis of 2-substituted benzo[f]isoindole-4,9-diones Tetrahedron, 69(43), 9033– 9037, 2013
9. Yu-jin Li,* Huan-ming Huang, Jie Ju, Jian-hong Jia, Liang Han, Qing Ye，Wu-bin Yu and Jian-rong Gao* Iodine mediated reaction of quinones and N-substituted amino esters to 2-substituted benzo[f]isoindole-4,9- diones RSC Adv., 3, 25840- 25848, 2013
-
教学与课程
研究生培养等教学情况：
主讲研究生课程：《精细有机合成及进展》，《绿色化学》，《功能有机色素》
本科生课程：
《有机化学C》，《无机及分析化学实验》
-
科研项目
主持的主要纵向项目：
1. 国家基金青年基金“基于桥环结构的新型氟硼吡咯类近红外荧光分子的创制与性能研究(21606201)”
2. 浙江省自然科学基金“有机功能色素材料的无溶剂绿色合成研究”（Y407306）
3. 浙江省自然科学基金：基于硼络合的稠氮杂环体系近红外荧光分子设计与绿色合成（LY13B020016）
主持的主要横向项目：
1. 蛋白酶的纯化，广州共禾医药科技有限公司, 50万，2014.8
2. 横埃索美拉唑的不对称氧化新工艺路线的开发, 广州共禾医药科技有限公司, 10万，2014.05
3. N,N-二甲氨基丙烯酸乙酯合成新工艺研究，台州黄岩荣升化工，10万2007.11
-
科研成果
发表的论文、专著、教材：
1.Meng-Ming Xing, Ming Xin, Chao Shen, Jian-Rong Gao, Jian-Hong Jia, Yu-Jin Li * Iodine-promotedoxidative coupling reaction: a simple and efficient process to access imidazo[1,2-a]pyridines from 2-aminopyridines and chalconesTetrahedron, 72(29), 4201-4204, 2016
2.Chao-jun Hua, Kan Zhang, Ming Xin, Ting Ying, Jian-rong Gao, Jian-hong Jia and Yu-jin Li* High quantum yield and pH sensitive fluorescence dyes based on coumarin derivatives: fluorescence characteristics and theoretical study RSC Adv., 6(54), 49221-49227, 2016
3. Meng-Ming Xing, Hui Xu, Li-Fen Hou, Jian-Rong Gao and Yu-Jin Li* AlCl3-catalyzed [3+3]cycloaddition of chalcones and beta-enamine ketones (esters): a highly efficient access to multisubstituted cyclohexa-1,3-dienaminesRSC Adv., 6(13), 10943-10948, 2016
4. Yujin Li, *HuiXu, Mingmemg Xing, Fang Huang, Jianhong Jia, Jianrong Gao Iodine-Promoted Construction of Polysubstituted 2,3-Dihydropyrroles from Chalcones and beta-Enamine Ketones (Esters) Org. Lett., 17 (15 ), 3690-3693, 2015
5. Jie Zheng, Yujin Li, *Yanhong Cui, Jianhong Jia,Qing Ye, Liang Han, Jianrong GaoIsatin-phenylhydrazone dyes and boron complexes with large Stokes shifts: synthesis and solid-state fluorescence characteristics Tetrahedron, 71, 3802-3809 2015
6. Jie Zheng, Fang Huang,Yujin Li, *Tianwei Xu, Hui Xu, Jianhong Jia,Qing Ye, Jianrong Gao The aggregation-induced emission enhancement properties of BF2 complex isatin-phenylhydrazone: Synthesis and fluorescence characteristics Dyes and Pigments,113, 502-509, 2015
7.Yu-Jin Li,* Huan-Ming Huang, Qing Ye, Li-Fen Hou, Wu-Bin Yu,Jian-Hong Jia, and JianRong Gao, * The Construction of Polysubstituted Aromatic Core Derivatives via a Cycloaddition/Oxidative Aromatization Sequnce from Quinone and b-Enamino Esters Adv. Synth. Catal., 356, 421 – 427, 2014
8. Huan-Ming Huang, Yu-Jin Li,* Qing Ye, Wu-Bin Yu, Liang Han, Jian-Hong Jia, and Jian-Rong Gao* Iodine-Catalyzed 1,3-Dipolar Cycloaddition/Oxidation/ Aromatization Cascade with Hydrogen Peroxide as the Terminal Oxidant: GeneralRoute to Pyrrolo[2,1-a]isoquinolinesJ. Org. Chem., 79 (3), 1084–1092, 2014
9.Yu-Jin Li,* Huan-Ming Huang, Hua-Qing Dong, Jian-Hong Jia, Liang Han, Qing Ye, and Jian-Rong Gao* The Synthesis of Benzo[f]isoindole-1,3-dicarboxylates via an I2-Induced 1,3-Dipolar Cycloaddition ReactionJ. Org. Chem., 78 (18), 9424– 9430, 2013
10.Huan-ming Huang, Yu-jin Li *, Jian-rong Yang, Jian-hong Jia, Qing Ye, Liang Han, Jianrong Gao * Efficient access to naphthoquinon-1,3-dithioles: formal cycloaddition and oxidation of quinones and amines with CS2 Tetrahedron, 69, 5221-5226, 2013
11.Huanming Huang, Jing Han, Fang Xu, Yujin Li,* Huaqing Dong, Wubin Yu, and Jianrong Gao* Facile One-pot Synthesis of Naphthoquinone1,3-Dithioles via 2,3- Dichlor-1,4-naphthoquinone and Amines Involving CS2 Chem. Lett.,42,921-923,2013
12.Huan-ming Huang, Jian-rong Gao, Li-fen Hou, Jian-hong Jia, Liang Han, Qing Ye, Yu-jin Li* The first iodine improved 1,3-dipolar cycloaddition: facile and novelsynthesis of 2-substituted benzo[f]isoindole-4,9-diones Tetrahedron,69(43), 9033– 9037, 2013
13.Yu-jin Li,* Huan-ming Huang, Jie Ju, Jian-hong Jia, Liang Han, Qing Ye，Wu-bin Yu and Jian-rong Gao* Iodine mediated reaction of quinones and N-substituted amino esters to 2-substituted benzo[f]isoindole-4,9- diones RSC Adv., 3, 25840- 25848, 2013
14. LI YuJin*, CAO YongWen, XU FengShuang, FANG WenMing, YU WuBin, JIA JianHong & GAO JianRong Solvent and catalyst free azo-Michael addition under high-speed vibration milling Sci China Chem, 55(7), 1252–1256, 2012
15. Li Yujin*, Huang Huanming, Gao Jianrong, Jia Jianhong, Dong Huaqing, Han Liang, Sheng Weijian, Research on the Solvent-Free Synthesis of Imidazo-[4,5-f] [1,10]-phenanthroline, Chin. J. Org.Chem., 31(8), 1286-1286, 2011.
科研成果及专利：
1. 李郁锦、高建荣、贾建洪、韩亮、盛卫坚、张森 一种β-氨基丙烯酮类化合物的合成方法 ZL200810060417.1
2. 李郁锦;高建荣;贾建洪;韩亮;盛卫坚;居洁 一种通过氧化卤化反应合成卤代化合物的方法 ZL200810062684.2
3. 李郁锦;高建荣;贾建洪;韩亮一种苯并二呋喃酮类化合物的绿色合成新工艺 ZL200910154596.X
4. 李郁锦;黄焕明;高建荣;贾建洪;盛卫坚;徐凤双 一种咪唑并菲咯啉类化合物的合成工艺 ZL201110072435.3
