蔡海婷

教育及工作经历：

2021.11-至今   浙江工业大学化学工程学院工业催化学科担任朝晖特聘副研究员

2020.09-2021.10 加拿大多伦多大学，化学工程专业，博士后

2014.09-2020.09 博士毕业于加拿大多伦多大学，化学工程专业，获加拿大安大略省Trillium 奖学金

2011.09-2014.06 硕士毕业于中国科学技术大学，有机化学专业

本人在博士及博士后期间主要从事过渡金属催化下加氢反应动力学等的研究。目前的研究方向为无汞催化下乙炔氢氯化反应机理的研究。

曾获化工学院第四届青年教师教学大比武特等奖（2023年）、浙江工业大学第二届教师教学设计大赛二等奖（2023年）。

发表论文

[1]  Su, Y.; Wang, S.; Ji, L.; Zhang, C.; Cai, H.; Zhang, H.; Sun, W., High surface area siloxene for photothermal and electrochemical catalysis. Nanoscale 2023, 15 (1), 154-161.

[2]  Zhang, D.; Cai, H.; Su, Y.; Sun, W.; Yang, D.; Ozin, G. A., Silica Samurai: Aristocrat of Energy and Environmental Catalysis. Chem Catalysis 2022, 2 (8), 1893-1918.

[3]  Tang, Q.; Yue, Y.; Jiang, Z.; Li, F.; Wang, T.; Jin, C.; Dong, H.; Chang, R.; Wang, B.; Cai, H.; Zhao, J.; Li, X., Non-metallic carbon-based catalysts for acetylene hydrochlorination: The effect of graphitization degree of carbonaceous material. Catal. Commun. 2022, 167, 106458.

[4]  Cai, H.; Schimmenti, R.; Gradiski, M. V.; Morris, R. H.; Mavrikakis, M.; Chin, Y.-H. C., Mechanistic Similarities and Differences for Hydrogenation of Aromatic Heterocycles and Aliphatic Carbonyls on Sulfided Ru Nanoparticles. ACS Catal. 2021, 11 (20), 12585-12608.

[5]  Cai, H.; Chin, Y.-H. C., Catalytic Effects of Chemisorbed Sulfur on Pyridine and Cyclohexene Hydrogenation on Pd and Pt Clusters. ACS Catal. 2021, 11 (3), 1684-1705.

[6]  Cai, H.; Schimmenti, R.; Nie, H.; Mavrikakis, M.; Chin, Y.-H. C., Mechanistic Role of the Proton-Hydride Pair in Heteroarene Catalytic Hydrogenation. ACS Catal. 2019, 9 (10), 9418-9437.

[7]  Cai, H.; Li, D.; Liu, Z.; Wang, G., Palladium-Catalyzed Decarboxylative ortho-Acylation of O-Methyl Ketoximes via Direct sp² C-H Bond Activation. Acta Chim. Sinica 2013, 71 (5), 717-721.

[8]  Li, F.; Jiang, T.; Cai, H.; Wang, G., Palladium‐Catalyzed Synthesis of Aromatic Sultones via Sulfonic Acid Group‐Directed C-H Activation. Chin. J. Chem. 2012, 30 (9), 2041-2046.

[9]  Cai, H.; Yuan, Z.; Zhu, W.; Zhu, G., Palladium-Catalyzed Haloallylation of Aromatic Ynol Ethers with Allyl Chlorides: A Highly Regio- and Stereoselective Approach to (1E)-α-Chloroenol Ethers. Chem. Commun. 2011, 47 (30), 8682-8684.

[10] Chen, X.; Kong, W.; Cai, H.; Kong, L.; Zhu, G., Palladium-Catalyzed Highly Regio- and Stereoselective Synthesis of (1E)- or (1Z)-1,2-Dihalo-1,4-Dienes via Haloallylation of Alkynyl Halides. Chem. Commun. 2011, 47 (7), 2164-2166.

[11] Chen, D.; Cao, Y.; Yuan, Z.; Cai, H.; Zheng, R.; Kong, L.; Zhu, G., Synthesis of cis-1,2-Dihaloalkenes Featuring Palladium-Catalyzed Coupling of Haloalkynes and α,β-Unsaturated Carbonyls. J. Org. Chem. 2011, 76 (10), 4071-4074.

[12] Chen, D.; Chen, X.; Lu, Z.; Cai, H.; Shen, J.; Zhu, G., Palladium-Catalyzed Dienylation of Haloalkynes using 2,3-Butadienyl Acetates: A Facile Access to (1Z)-1,2-Dihalo-3-vinyl-1,3-dienes. Adv. Synth. Catal. 2011, 353 (9), 1474-1478.

国际会议报告(*标注为大会现场报告者)

·     口头报告

-      美国化学会秋季会议(American Chemical Society Fall National Meeting) 2021年8月

Cai, H.*; Schimmenti, R.; Gradiski, M.; Morris, R. H.; Mavrikakis, M.; Chin, Y.-H. C., Contrasting reactivity trends of hydrogenation of aromatic and carbonyl compounds on sulfided Ru catalysts. ACS Fall National Meeting, Atlanta, GA, United States, August 22-26, 2021. 

-     第25届加拿大催化学术会议 (25^th Canadian Symposium on Catalysis) 2018年5月

Cai, H.*; Chin, Y.-H. C., The Kinetic Study of Hydrogenation of Basic and Non-Basic N-Rings on Ru Sulfide Clusters. The 25^th Canadian Symposium of Catalysis, Saskatoon, Saskatchewan, Canada, May 8-11, 2018.

-     第25届北美催化学术会议 (25^th North American Catalysis Society Meeting) 2017年6月

Cai, H.*; Chin, Y.-H. C., Mechanistic Studies of Hydrodenitrogenation of Basic and Non-Basic Organo-Nitrogen Compounds on Ru Clusters. 25^th North American Catalysis Society Meeting (NAM) in Denver, CO, United States, June 4-9, 2017.

·     展报报告

-      第40届密西根催化论坛（40^th Annual MC-NACS Spring Symposium）2019年5月

Cai, H.*; Schimmenti R.; Nie, H.; Mavrikakis, M.; Chin, Y.-H. C., Catalytic Significance of Proton-Hydride Pair during Pyridine and Pyrrole Hydrogenation on Sulfided Ru Clusters. 40^th Annual MC-NACS Spring Symposium, Dearborn, MI, United States, May 7, 2019.

-     高登研究会议（Gordon Research Conference）2016年6月

Cai, H.*; Chin, Y.-H. C., Mechanistic Investigation of Pyridine Hydrogenation on Dispersed Ruthenium. Gordon Research Conference in New London, NH, United States, June 12-17, 2016.

-      第十届全国物理有机化学学术会议 2013年9月

Cai, H.*; Li, D.; Liu, Z.; Wang, G., Palladium-Catalyzed Decarboxylative ortho-Acylation of O-Methyl Ketoximesvia Direct sp² C-H Bond Activation.10^th National Conference on Physical Organic Chemistry, Hefei, China, September 13-14, 2013. 

目前承担国家自然科学基金青年基金项目：《离子液体修饰的铜基等非贵金属催化剂作用下乙炔氢氯化反应活性趋势的研究》（2023.01-2025.12）

教学与课程：

《催化科学与技术（留学生）》、《化工智能材料与资源开发》