沈海民,男,中山大学工学博士,教授,硕士生导师,博士生导师,1983年04月出生于河北省张家口市蔚县。长期从事精细化工,绿色化学,仿生催化,催化氧化,催化还原研究。主持完成国家自然科学基金青年基金项目1项,主持国家自然科学基金面上项目2项,参与承担国家自然科学基金青年基金项目1项,参与承担国家自然科学基金面上项目1项。主持企业横向课题4项。在Chemical Engineering Journal、Chemical Engineering Science、Applied Catalysis A, General、Applied Surface Science、RSC Advances、New Journal of Chemistry、Catalysis Communications、Molecular Catalysis等国内外学术期刊上发表学术论文40余篇,申请中国发明专利40余件,授权中国发明专利11件,授权美国发明专利1件。主讲本科生专业必修课程绿色化工技术,化工安全与环境。浙江工业大学优秀班主任。浙江工业大学优秀教师。浙江工业大学优秀本科毕业论文指导教师。指导研究生获国家奖学金3人次,指导研究生获浙江工业大学一等学业奖学金15人次以上。
学习经历:
2002.09-2006.06,浙江工业大学,化学工程学院,化学工程与工艺专业,精细化工模块,获工学学士学位
2006.09-2009.06,浙江工业大学,化学工程学院,应用化学专业,精细有机合成方向,获工学硕士学位(保送),师从史鸿鑫教授
2009.09-2012.06,中山大学,化学与化学工程学院,材料物理与化学专业,环境友好的化工过程及仿生催化方向,获工学博士学位,师从纪红兵教授
工作经历:
2012.10-2016.12,浙江工业大学,化学工程学院,讲师,佘远斌教授团队
2016.12-2018.12,浙江工业大学,化学工程学院,副教授,硕士生导师,佘远斌教授团队
2019.01-2023.12,浙江工业大学,化学工程学院,副教授,硕士生导师,博士生导师,佘远斌教授团队
2023年12月至今,浙江工业大学,化学工程学院,教授,硕士生导师,博士生导师,佘远斌教授团队
主持项目:
1. 环糊精-Fe3O4超分子仿生催化体系的构筑及其对水相不对称反应的调控,国家自然科学基金青年基金项目,2013.01.01-2016.12.31,主持
2. 双金属卟啉协同催化氧气选择性氧化环烷烃合成醇、酮研究,国家自然科学基金面上项目,2019.01.01-2022.12.31,主持
3. 限域环境中双金属中心接力催化O2选择氧化烃类C-H键规律的研究,国家自然科学基金面上项目,2022.01.01- 2025.12.31,主持
4. 一种防晒剂A二钠盐合成工艺的开发,企业横向课题,75.0万,主持
5. 无水家用机洗洗衣液配方的研究和开发,企业横向课题,5.0万,主持
6. 关键医药中间体的工艺研发,企业横向课题,100.0万,主持
7. 电化铝烫印箔水溶性色料配方开发和涂布工艺改进,企业横向课题,10.0万,主持
主要学术论文:
[41] Jia-Ye Ni, Yan-Bo Ding, Jing Sun, Hong-Ke Wu, Hai-Min Shen*, Yuan-Bin She*. Cycloalkanes oxidation with O2 catalyzed by a novel metalloporphyrin -based covalent coupling structure with bimetallic catalytic centers through synergistic mode [J]. Catalysis Communications, 2024, 187: 106876.
[40] Yu Zhang, Xiao-Ling Feng, Jia-Ye Ni, Bo Fu, Hai-Min Shen*, Yuan-Bin She*. Efficient Inhibition of Deep Conversion of Partial Oxidation Products in C-H Bonds′ Functionalization Utilizing O2 via Relay Catalysis of Dual Metalloporphyrins on Surface of Hybrid Silica Possessing Capacity for Product Exclusion [J]. Biomimetics, 2024, 9: 272.
[39] Yuan-Bin She, Yu Zhang, Jia-Ye Ni, Xin-Yan Zhou, Hong-Liang Ye, Hai-Min Shen*. Practical and efficient oxygenation of benzylic C-H bonds with dioxygen catalyzed by two-dimensional porous organic frameworks possessing porphyrin cobalt(II) units [J]. Chemical Engineering Science, 2024, 293: 120056.
[38] Yu Zhang, Bo Fu, Jing Sun, Yan-Bo Ding, Hai-Min Shen*, Yuan-Bin She*. Relay catalysis on the surface of hybrid silica functionalized with dual metalloporphyrins(Co&Zn) for efficient and selective oxygenation of cycloalkanes using oxygen [J]. Molecular Catalysis, 2024, 557: 113957.
[37] Xin-Yan Zhou, Bo Fu, Wen-Dong Jin, Xiong Wang, Ke-Ke Wang , Mei Wang, Yuan-Bin She, Hai-Min Shen*. Efficient and Selective Oxygenation of Cycloalkanes and Alkyl Aromatics with Oxygen through Synergistic Catalysis of Bimetallic Active Centers in Two-Dimensional Metal-Organic Frameworks Based on Metalloporphyrins [J]. Biomimetics, 2023, 8(3): 325.
[36] Jia-Ye Ni, Bin He, Hao Huang, Lei Ning, Qiu-Ping Liu, Ke-Ke Wang, Hong-Ke Wu, Hai-Min Shen*, Yuan-Bin She*. Cycloalkanes oxidation with O2 in high-efficiency and high-selectivity catalyzed by 3D MOFs with limiting domain and Zn(AcO)2 through synergistic mode [J]. Molecular Catalysis, 2023, 540: 113027.
[35] Xin-Yan Zhou, Bin He, Yu Zhang, Jia-Ye Ni, Qiu-Ping Liu, Mei Wang, Hai-Min Shen*, Yuan-Bin She*. Selective and Efficient Catalytic Oxygenation of Alkyl Aromatics Employing H2O2 Catalyzed by Simple Porphyrin Iron(II) under Mild Conditions [J]. Processes, 2023, 11: 1187.
[34] Hai-Min Shen, Hong-Liang Ye, Jia-Ye Ni, Ke-Ke Wang, Xin-Yan Zhou, Yuan-Bin She*. Oxidation of α-C-H bonds in alkyl aromatics with O2 catalyzed by highly dispersed cobalt(II) coordinated in confined reaction channel of porphyrin-based POFs with simultaneously enhanced conversion and selectivity [J]. Chemical Engineering Science, 2023, 270: 118472.
[33] A-Bing Guo, Jia-Wei Qin, Ke-Ke Wang, Qiu-Ping Liu, Hong-Ke Wu, Mei Wang, Hai-Min Shen*, Yuan-Bin She. Synergetic catalytic oxidation of C-H bonds in cycloalkanes and alkyl aromatics by dimetallic active sites in 3D metalloporphyrinic MOFs employing O2 as oxidant with increased conversion and unconsumed selectivity [J]. Molecular Catalysis, 2023, 535:112853.
[32] Hai-Min Shen, Xiong Wang, Hao Huang, Qiu-Ping Liu, Dong Lv, Yuan-Bin She*. Staged oxidation of hydrocarbons with simultaneously enhanced conversion and selectivity employing O2 as oxygen source catalyzed by 2D metalloporphyrin-based MOFs possessing bimetallic active centers [J]. Chemical Engineering Journal, 2022, 443: 136126.
[31] Hai-Min Shen, A-Bing Guo, Yu Zhang, Qiu-Ping Liu, Jia-Wei Qin, Yuan-Bin She*. Relay catalysis of hydrocarbon oxidation using O2 in the confining domain of 3D metalloporphyrin-based metal-organic frameworks with bimetallic catalytic centers [J]. Chemical Engineering Science, 2022, 260: 117825.
[30] Jia-Ye Ni, Shu-Zhen Cong, Lei Ning, Mei Wang, Hai-Min Shen*, Yuan-Bin She*. Binary catalytic systems constructed by porphyrin cobalts(II) with confining nano-region and Zn(OAc)2 for oxygenation of cycloalkanes with O2 in relay mode [J]. Molecular Catalysis, 2022, 531:112676.
[29] Hai-Min Shen, Xiong Wang, Lei Ning, A-Bing Guo, Jin-Hui Deng, Yuan-Bin She*. Efficient oxidation of cycloalkanes with simultaneously increased conversion and selectivity using O2 catalyzed by metalloporphyrins and boosted by Zn(AcO)2: A practical strategy to inhibit the formation of aliphatic diacids [J]. Applied Catalysis A, General, 2021, 609: 117904.
[28] Hai-Min Shen, Hong-Liang Ye, Qin Wang, Meng-Yun Hu, Lei Liu, Yuan-Bing She*. Efficient oxidation of cumene to cumene hydroperoxide with ambient O2 catalyzed by metalloporphyrins [J]. Journal of Porphyrins and Phthalocyanines, 2021, 25: 314-322.
[27] Hai-Min Shen, Meng-Yun Hu, Lei Liu, Bei Qi, Hong-Liang Ye, Yuan-Bin She*. Efficient and selective oxidation of tertiary benzylic C-H bonds with O2 catalyzed by metalloporphyrins under mild and solvent-free conditions [J]. Applied Catalysis A, General, 2020, 599: 117599.
[26] Hai-Min Shen, Bei Qi, Meng‑Yun Hu, Lei Liu, Hong‑Liang Ye, Yuan‑Bin She*. Selective Solvent-Free and Additive-Free Oxidation of Primary Benzylic C-H Bonds with O2 Catalyzed by the Combination of Metalloporphyrin with N‑Hydroxyphthalimide [J]. Catalysis Letters, 2020, 150: 3096-3111.
[25] Hai-Min Shen*, Lei Liu, Bei Qi, Meng-Yun Hu, Hong-Liang Ye, Yuan-Bin She. Efficient and selective oxidation of secondary benzylic C-H bonds to ketones with O2 catalyzed by metalloporphyrins under solvent-free and additive-free conditions [J]. Molecular Catalysis, 2020, 493: 111102.
[24] Hai-Min Shen, Xiong Wang, A-Bing Guo, Long Zhang, Yuan-Bing She*. Catalytic oxidation of cycloalkanes by porphyrin cobalt(II) through efficient utilization of oxidation intermediates [J]. Journal of Porphyrins and Phthalocyanines, 2020, 24: 1166-1173.
[23] Hai-Min Shen, Long Zhang, Jin-Hui Deng, Jing Sun, Yuan-Bin She*. Enhanced catalytic performance of porphyrin cobalt(II) in the solvent-free oxidation of cycloalkanes (C5~C8) with molecular oxygen promoted by porphyrin zinc(II) [J]. Catalysis Communications, 2019, 132: 105809 .
[22] Hai-Min Shen, Yan Wang, Jin-Hui Deng, Long Zhang, Yuan-Bin She*. Catalyst-free and solvent-free oxidation of cycloalkanes (C5-C8) with molecular oxygen: Determination of autoxidation temperature and product distribution[J]. Chinese Journal of Chemical Engineerin,2018,26(5):1064-1070.
[21] 佘远斌,邓金辉,张龙,沈海民*. 氧气催化氧化环己烷[J].化学进展,2018,30(1):124-136.
[20] 沈海民,王岩,佘远斌*.金属卟啉催化氧化环己烷最新研究进展[J].化工进展,2018,37(6):2031-2045.
[19] 韩叶强,周文杰,沈海民*,刘秋平,于文艳,纪红兵,佘远斌*.固载化β-环糊精吸附环境污染物的研究进展[J].有机化学,2016,36(2):248-257.
[18] Hai-Min Shen*,Wen-Jie Zhou,Wu-Bin Yu,Hong-Ke Wu,Qiu-Ping Liu,Hong-Bing Ji,Yan Wang,Yuan-Bin She*.Metal-free chemoselective oxidation of sulfides to sulfoxides catalyzed by immobilized L-aspartic acid and L-glutamic acid in an aqueous phase at room temperature[J].New Journal of Chemistry,2016,40(6):4874-4878.
[17] 沈海民*,武宏科,史鸿鑫,纪红兵,余武斌*.非均相环糊精在水相有机合成反应中的应用[J].化学进展,2015,27(1):70-78.
[16] 沈海民*,方红果,武宏科,纪红兵,史鸿鑫*.环糊精衍生物的分子形态及其构筑策略研究进展[J].化工进展,2015,34(2):430-446.
[15] Hai-Min Shen*,Wen-Jie Zhou,Hong-Ke Wu,Wu-Bin Yu,Ning Ai,Hong-Bing Ji,Hong-Xin Shi,Yuan-Bin She*.Metal-free chemoselective oxidation of sulfides to sulfoxides catalyzed by immobilized taurine and homotaurine in aqueous phase at room temperature[J].Tetrahedron Letters,2015,56(30):4494-4498.
[14] Hai-Min Shen*,Wen-Jie Zhou,Xin Ma,Hong-Ke Wu,Wu-Bin Yu,Ning Ai,Hong-Bing Ji,Hong-Xin Shi, Yuan-Bin She*.pH-Dependence of the Aqueous Phase Room Temperature Brønsted Acid-Catalyzed Chemoselective Oxidation of Sulfides with H2O2[J].Molecules,2015,20(9):16709-16722.
[13] Hai-Min Shen,Gong-Yuan Zhu,Wu-Bin Yu,Hong-Ke Wu,Hong-Bing Ji, Hong-Xin Shi,Yi-Fan Zheng*,Yuan-Bin She*.Surface immobilization of β-cyclodextrin on hybrid silica and its fast adsorption performance of p-nitrophenol from the aqueous phase[J].RSC Advances,2015,5(103):84410-84422.
[12] Hai-Min Shen*,Gong-Yuan Zhu,Wu-Bin Yu,Hong-Ke Wu,Hong-Bing Ji,Hong-Xin Shia,Yuan-Bin She,Yi-Fan Zheng.Fast adsorption of p-nitrophenol from aqueous solution using β-cyclodextrin grafted silica gel[J].Applied Surface Science,2015,356:1155-1167.
[11] 沈海民*,武宏科,纪红兵,史鸿鑫*. β-环糊精-Fe3O4超分子体系的构筑及其应用研究进展[J].有机化学,2014,34(4):630-646.
[10] 沈海民*,纪红兵,武宏科,史鸿鑫*.β-环糊精的固载及其应用最新研究进展[J].有机化学,2014,34(8):1549-1572.
[9] Hai-Min Shen,Hong-Bing Ji*. Cyclodextrine-[RuCl2(Arene)]2 conjugates: another way to enhancethe enantioselectivity of aromatic ketones reduction by aromatic ligands’ volume[J].Tetrahedron,2013,69(39):8360-8367.
[8] Hai-Min Shen,Hong-Bing Ji*.Amino alcohol-modified β-cyclodextrin inducing biomimetic asymmetric oxidation of thioanisole in water[J].Carbohydrate Research,2012,354:49-58.
[7] 沈海民,纪红兵*.环糊精衍生物在金属催化有机合成中的应用[J].有机化学,2012,32(6):975-985.
[6] Hai-Min Shen,Hong-Bing Ji*.Biomimetic asymmetric aldol reactions catalyzed by proline derivatives attached to β-cyclodextrin in water[J].Tetrahedron Letters,2012,53(28):3541-3545.
[5] 沈海民,纪红兵*. β-环糊精衍生物诱导Na2MoO4催化H2O2不对称氧化苯甲硫醚[J].有机化学,2012,32(9):1684-1689.
[4] 沈海民,纪红兵*.环糊精衍生物在液相有机合成中的应用[J].有机化学,2011,31(6):791-803.
[3] 沈海民,史鸿鑫*,武宏科,项菊萍,朱春凤.N-(p-全氟壬烯氧基苯磺酰基)肌氨酸钠的合成与表面活性[J]. 高校化学工程学报,2009,23(4):679-683.
[2] 沈海民,史鸿鑫*,项菊萍,刘秋平,朱春凤.硫酸酯型氟表面活性剂的合成与表面活性[J].应用化学,2009,26(9):1036-1039.
[1] 沈海民,史鸿鑫*,武宏科,项菊萍.对全氟壬烯氧基苯磺酸钠的合成与表面活性[J].农药,2007,46(8):520-522.
授权专利:
[12] 沈海民,张羽,孙静. 一种双金属中心金属卟啉及其制备方法和应用[P]. 申请号:202010884408.5, 申请日:2020.08.28. 申请公布号:CN112090449A, 申请公布日:2020.12.18. 授权公告号:CN112090449B,专利号:ZL 202010884408.5,授权公告日:2023.03.31. 申请人:浙江工业大学.
[11] 沈海民,黄浩. 一种三金属中心(Co&Cu&Zn)2DMOFs/紫外光催化氧化环烷烃的方法[P]. 申请号:202111006432.X, 申请日:2021.08.30. 申请公布号:CN113603564A, 申请公布日:2021.11.05. 授权公告号:CN113603564B,专利号:ZL 202111006432.X,授权公告日:2023.03.14. 申请人:浙江工业大学.
[10] 沈海民,黄浩. 一种金属卟啉三金属中心2DMOFs及其制备方法和应用[P]. 申请号:202111008838.1, 申请日:2021.08.31. 申请公布号:CN113683619A, 申请公布日:2021.11.23. 授权公告号:CN113683619B,专利号:ZL 202111008838.1,授权公告日:2023.07.14. 申请人:浙江工业大学.
[9] Hai-Min Shen, Lei Ning, Yuan-Bin She. Confined Porphyrin Co(II) and Preparation Method and Application Thereof [P]. Patent No.: US11420991(B2), Date of Patent: 2022-08-23. Applicant: Zhejiang University of Technology.
[8] 沈海民,任文山. 一种Cu(II)/硝酸二元催化体系催化O2氧化环己烯一步合成己二酸的方法[P]. 申请号:2021109811098, 申请日:2021.08.25. 申请公布号:CN113563176A, 申请公布日:2021.10.29. 专利号:ZL 2021109811098,授权公告号:CN113563176B,授权公告日:2022.12.20. 申请人:浙江工业大学.
[7] 沈海民,丛淑贞. 封端3D钴(II)卟啉POF材料及其制备方法和应用[P]. 申请号:2021109875009, 申请日:2021.08.26. 申请公布号:CN113717394A, 申请公布日:2021.11.30. 专利号: 2021109875009. 授权公告号:CN113717394B,授权公告日:2022.06.03. 申请人:浙江工业大学.
[6] 沈海民,宁磊,佘远斌. 一种限域性卟啉Co(II)及其制备方法和应用[P]. 申请号:2019111619249, 申请日:2019.11.25. 申请公布号:CN110938078A, 申请公布日:2020.03.31. 专利号: 2019111619249. 授权公告号:CN110938078B,授权公告日:2021.01.01. 申请人:浙江工业大学.
[5] 沈海民,齐备,佘远斌. 甲苯类化合物选择性氧化的方法[P]. 申请号:2019108011331, 申请日:2019.08.28. 申请公布号:CN110563590A, 申请公布日:2019.12.13. 专利号: 2019108011331. 授权公告号:CN110563590B,授权公告日:2022.03.18. 申请人:浙江工业大学.
[4] 沈海民, 叶宏亮, 佘远斌. 一种乙苯及其衍生物选择性氧化制备苯乙酮及其衍生物的方法[P]. 申请号:2019107949087, 申请日:2019.08.27. 申请公布号:CN110498745A, 申请公布日:2019.11.26. 专利号: 2019107949087. 授权公告号:CN110498745B,授权公告日:2022.06.17. 申请人:浙江工业大学.
[3] 沈海民, 史鸿鑫, 武宏科. 一种不锈钢氧化层清洗剂及其制备方法和应用[P]. 申请号:2014100424102, 申请日:2014.01.28. 申请公布号:CN103820797A, 申请公布日: 2014.05.28. 申请人:浙江工业大学. 授权专利号: 2014100424102, 授权公告号: CN103820797B, 授权日: 2016.05.18.
[2] 佘远斌, 刘磊, 沈海民. 一种乙苯类化合物选择性氧化的方法[P]. 申请号:2019108011346, 申请日:2019.08.28. 申请公布号:CN110483222A, 申请公布日:2019.11.22. 专利号: 2019108011346. 授权公告号:CN110483222B,授权公告日:2022.06.21. 申请人:浙江工业大学.
[1] 佘远斌, 胡梦云, 沈海民. 一种异丙苯类化合物选择性氧化的方法[P]. 申请号:2019108011327, 申请日:2019.08.28. 申请公布号:CN110423185A, 申请公布日:2019.11.08. 专利号: 2019108011327. 授权公告号:CN110423185B,授权公告日:2022.03.18. 申请人:浙江工业大学.