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更新时间:2024.08.20
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沈海民

| 博士 教授 博士生导师

单位: 化学工程学院

职务: 教研室主任

研究方向:

办公地址: 莫干山校区化工学院5-C413

办公电话: 15988460002

电子邮箱: haimshen@zjut.edu.cn

手机访问
  • 个人简介

    沈海民,男,中山大学工学博士,教授,硕士生导师,博士生导师,1983年04月出生于河北省张家口市蔚县。长期从事精细化工,绿色化学,仿生催化,催化氧化,催化还原研究。主持完成国家自然科学基金青年基金项目1项,主持国家自然科学基金面上项目2项,参与承担国家自然科学基金青年基金项目1项,参与承担国家自然科学基金面上项目1项。主持企业横向课题4项。在Chemical Engineering Journal、Chemical Engineering Science、Applied Catalysis A, GeneralApplied Surface ScienceRSC AdvancesNew Journal of ChemistryCatalysis CommunicationsMolecular Catalysis等国内外学术期刊上发表学术论文40余篇,申请中国发明专利40余件,授权中国发明专利11件,授权美国发明专利1件。主讲本科生专业必修课程绿色化工技术,化工安全与环境。浙江工业大学优秀班主任。浙江工业大学优秀教师。浙江工业大学优秀本科毕业论文指导教师。指导研究生获国家奖学金3人次,指导研究生获浙江工业大学一等学业奖学金15人次以上。


    学习经历:

    2002.09-2006.06,浙江工业大学,化学工程学院,化学工程与工艺专业,精细化工模块,获工学学士学位

    2006.09-2009.06,浙江工业大学,化学工程学院,应用化学专业,精细有机合成方向,获工学硕士学位(保送),师从史鸿鑫教授

    2009.09-2012.06,中山大学,化学与化学工程学院,材料物理与化学专业,环境友好的化工过程及仿生催化方向,获工学博士学位,师从纪红兵教授

     

    工作经历:

    2012.10-2016.12,浙江工业大学,化学工程学院,讲师,佘远斌教授团队

    2016.12-2018.12,浙江工业大学,化学工程学院,副教授,硕士生导师,佘远斌教授团队

    2019.01-2023.12,浙江工业大学,化学工程学院,副教授,硕士生导师,博士生导师,佘远斌教授团队

    2023年12月至今,浙江工业大学,化学工程学院,教授,硕士生导师,博士生导师,佘远斌教授团队

     

    主持项目:

    1.  环糊精-Fe3O4超分子仿生催化体系的构筑及其对水相不对称反应的调控,国家自然科学基金青年基金项目,2013.01.01-2016.12.31,主持

    2.  双金属卟啉协同催化氧气选择性氧化环烷烃合成醇、酮研究,国家自然科学基金面上项目,2019.01.01-2022.12.31,主持

    3.  限域环境中双金属中心接力催化O2选择氧化烃类C-H键规律的研究,国家自然科学基金面上项目,2022.01.01- 2025.12.31,主持

    4.  一种防晒剂A二钠盐合成工艺的开发,企业横向课题,75.0,主持

    5.  无水家用机洗洗衣液配方的研究和开发,企业横向课题,5.0,主持

    6.  关键医药中间体的工艺研发,企业横向课题,100.0,主持

    7.  电化铝烫印箔水溶性色料配方开发和涂布工艺改进,企业横向课题,10.0,主持

     

    主要学术论文:

    [41] Jia-Ye Ni, Yan-Bo Ding, Jing Sun, Hong-Ke Wu, Hai-Min Shen*, Yuan-Bin She*. Cycloalkanes oxidation with O2 catalyzed by a novel metalloporphyrin -based covalent coupling structure with bimetallic catalytic centers through synergistic mode [J]. Catalysis Communications, 2024, 187: 106876.

    [40] Yu Zhang, Xiao-Ling Feng, Jia-Ye Ni, Bo Fu, Hai-Min Shen*, Yuan-Bin She*. Efficient Inhibition of Deep Conversion of Partial Oxidation Products in C-H Bonds′ Functionalization Utilizing O2 via Relay Catalysis of Dual Metalloporphyrins on Surface of Hybrid Silica Possessing Capacity for Product Exclusion [J]. Biomimetics, 2024, 9: 272.

    [39] Yuan-Bin She, Yu Zhang, Jia-Ye Ni, Xin-Yan Zhou, Hong-Liang Ye, Hai-Min Shen*. Practical and efficient oxygenation of benzylic C-H bonds with dioxygen catalyzed by two-dimensional porous organic frameworks possessing porphyrin cobalt(II) units [J]. Chemical Engineering Science, 2024, 293: 120056.

    [38] Yu Zhang, Bo Fu, Jing Sun, Yan-Bo Ding, Hai-Min Shen*, Yuan-Bin She*. Relay catalysis on the surface of hybrid silica functionalized with dual metalloporphyrins(Co&Zn) for efficient and selective oxygenation of cycloalkanes using oxygen [J]. Molecular Catalysis, 2024, 557: 113957.

    [37] Xin-Yan Zhou, Bo Fu, Wen-Dong Jin, Xiong Wang, Ke-Ke Wang , Mei Wang, Yuan-Bin She, Hai-Min Shen*. Efficient and Selective Oxygenation of Cycloalkanes and Alkyl Aromatics with Oxygen through Synergistic Catalysis of Bimetallic Active Centers in Two-Dimensional Metal-Organic Frameworks Based on Metalloporphyrins [J]. Biomimetics, 2023, 8(3): 325.

    [36] Jia-Ye Ni, Bin He, Hao Huang, Lei Ning, Qiu-Ping Liu, Ke-Ke Wang, Hong-Ke Wu, Hai-Min Shen*, Yuan-Bin She*. Cycloalkanes oxidation with O2 in high-efficiency and high-selectivity catalyzed by 3D MOFs with limiting domain and Zn(AcO)2 through synergistic mode [J]. Molecular Catalysis, 2023, 540: 113027.

    [35] Xin-Yan Zhou, Bin He, Yu Zhang, Jia-Ye Ni, Qiu-Ping Liu, Mei Wang, Hai-Min Shen*, Yuan-Bin She*. Selective and Efficient Catalytic Oxygenation of Alkyl Aromatics Employing H2O2 Catalyzed by Simple Porphyrin Iron(II) under Mild Conditions [J]. Processes, 2023, 11: 1187.

    [34] Hai-Min Shen, Hong-Liang Ye, Jia-Ye Ni, Ke-Ke Wang, Xin-Yan Zhou, Yuan-Bin She*. Oxidation of α-C-H bonds in alkyl aromatics with O2 catalyzed by highly dispersed cobalt(II) coordinated in confined reaction channel of porphyrin-based POFs with simultaneously enhanced conversion and selectivity [J]. Chemical Engineering Science, 2023, 270: 118472.

    [33] A-Bing Guo, Jia-Wei Qin, Ke-Ke Wang, Qiu-Ping Liu, Hong-Ke Wu, Mei Wang, Hai-Min Shen*, Yuan-Bin She. Synergetic catalytic oxidation of C-H bonds in cycloalkanes and alkyl aromatics by dimetallic active sites in 3D metalloporphyrinic MOFs employing O2 as oxidant with increased conversion and unconsumed selectivity [J]. Molecular Catalysis, 2023, 535:112853.

    [32] Hai-Min Shen, Xiong Wang, Hao Huang, Qiu-Ping Liu, Dong Lv, Yuan-Bin She*. Staged oxidation of hydrocarbons with simultaneously enhanced conversion and selectivity employing O2 as oxygen source catalyzed by 2D metalloporphyrin-based MOFs possessing bimetallic active centers [J]. Chemical Engineering Journal, 2022, 443: 136126.

    [31] Hai-Min Shen, A-Bing Guo, Yu Zhang, Qiu-Ping Liu, Jia-Wei Qin, Yuan-Bin She*. Relay catalysis of hydrocarbon oxidation using O2 in the confining domain of 3D metalloporphyrin-based metal-organic frameworks with bimetallic catalytic centers [J]. Chemical Engineering Science, 2022, 260: 117825.

    [30] Jia-Ye Ni, Shu-Zhen Cong, Lei Ning, Mei Wang, Hai-Min Shen*, Yuan-Bin She*. Binary catalytic systems constructed by porphyrin cobalts(II) with confining nano-region and Zn(OAc)2 for oxygenation of cycloalkanes with O2 in relay mode [J]. Molecular Catalysis, 2022, 531:112676.

    [29] Hai-Min Shen, Xiong Wang, Lei Ning, A-Bing Guo, Jin-Hui Deng, Yuan-Bin She*. Efficient        oxidation of cycloalkanes with simultaneously increased conversion and selectivity using O2 catalyzed by metalloporphyrins and boosted by Zn(AcO)2: A practical strategy to inhibit the formation of aliphatic diacids [J]. Applied Catalysis A, General, 2021, 609: 117904.

    [28] Hai-Min Shen, Hong-Liang Ye, Qin Wang, Meng-Yun Hu, Lei Liu, Yuan-Bing She*. Efficient oxidation of cumene to cumene hydroperoxide with ambient O2 catalyzed by metalloporphyrins [J]. Journal of Porphyrins and Phthalocyanines, 2021, 25: 314-322.

    [27] Hai-Min Shen, Meng-Yun Hu, Lei Liu, Bei Qi, Hong-Liang Ye, Yuan-Bin She*. Efficient and selective oxidation of tertiary benzylic C-H bonds with Ocatalyzed by metalloporphyrins under mild and solvent-free conditions [J]. Applied Catalysis A, General, 2020, 599: 117599.

    [26] Hai-Min Shen, Bei Qi, MengYun Hu, Lei Liu, HongLiang Ye, YuanBin She*. Selective Solvent-Free and Additive-Free Oxidation of Primary Benzylic C-H Bonds with O2 Catalyzed by the Combination of Metalloporphyrin with NHydroxyphthalimide [J]. Catalysis Letters, 2020, 150: 3096-3111.

    [25] Hai-Min Shen*, Lei Liu, Bei Qi, Meng-Yun Hu, Hong-Liang Ye, Yuan-Bin She. Efficient and selective oxidation of secondary benzylic C-H bonds to ketones with O2 catalyzed by metalloporphyrins under solvent-free and additive-free conditions [J]. Molecular Catalysis, 2020, 493: 111102.

    [24] Hai-Min Shen, Xiong Wang, A-Bing Guo, Long Zhang, Yuan-Bing She*. Catalytic oxidation of cycloalkanes by porphyrin cobalt(II) through efficient utilization of oxidation intermediates [J]. Journal of Porphyrins and Phthalocyanines, 2020, 24: 1166-1173.

    [23] Hai-Min Shen, Long Zhang, Jin-Hui Deng, Jing Sun, Yuan-Bin She*. Enhanced catalytic performance of porphyrin cobalt(II) in the solvent-free oxidation of cycloalkanes (C5~C8) with molecular oxygen promoted by porphyrin zinc(II) [J]. Catalysis Communications, 2019, 132: 105809 .

    [22] Hai-Min Shen, Yan Wang, Jin-Hui Deng, Long Zhang, Yuan-Bin She*. Catalyst-free and solvent-free oxidation of cycloalkanes (C5-C8) with molecular oxygen: Determination of autoxidation temperature and product distribution[J]. Chinese Journal of Chemical Engineerin201826(5)1064-1070.

    [21] 佘远斌,邓金辉,张龙,沈海民*. 氧气催化氧化环己烷[J].化学进展,201830(1)124-136.

    [20] 沈海民,王岩,佘远斌*.金属卟啉催化氧化环己烷最新研究进展[J].化工进展,201837(6)2031-2045.

    [19] 韩叶强,周文杰,沈海民*,刘秋平,于文艳,纪红兵,佘远斌*.固载化β-环糊精吸附环境污染物的研究进展[J].有机化学,201636(2)248-257.

    [18] Hai-Min Shen*Wen-Jie ZhouWu-Bin YuHong-Ke WuQiu-Ping LiuHong-Bing JiYan WangYuan-Bin She*.Metal-free chemoselective oxidation of sulfides to sulfoxides catalyzed by immobilized L-aspartic acid and L-glutamic acid in an aqueous phase at room temperature[J].New Journal of Chemistry201640(6)4874-4878.

    [17] 沈海民*,武宏科,史鸿鑫,纪红兵,余武斌*.非均相环糊精在水相有机合成反应中的应用[J].化学进展,201527(1)70-78.

    [16] 沈海民*,方红果,武宏科,纪红兵,史鸿鑫*.环糊精衍生物的分子形态及其构筑策略研究进展[J].化工进展,201534(2)430-446.

    [15] Hai-Min Shen*Wen-Jie ZhouHong-Ke WuWu-Bin YuNing AiHong-Bing JiHong-Xin ShiYuan-Bin She*.Metal-free chemoselective oxidation of sulfides to sulfoxides catalyzed by immobilized taurine and homotaurine in aqueous phase at room temperature[J].Tetrahedron Letters201556(30)4494-4498.

    [14] Hai-Min Shen*Wen-Jie ZhouXin MaHong-Ke WuWu-Bin YuNing AiHong-Bing JiHong-Xin Shi Yuan-Bin She*.pH-Dependence of the Aqueous Phase Room Temperature Brønsted Acid-Catalyzed Chemoselective Oxidation of Sulfides with H2O2[J].Molecules201520(9)16709-16722.

    [13] Hai-Min ShenGong-Yuan ZhuWu-Bin YuHong-Ke WuHong-Bing Ji   Hong-Xin ShiYi-Fan Zheng*Yuan-Bin She*.Surface immobilization of β-cyclodextrin on hybrid silica and its fast adsorption performance of p-nitrophenol from the aqueous phase[J].RSC Advances20155(103)84410-84422. 

    [12] Hai-Min Shen*Gong-Yuan ZhuWu-Bin YuHong-Ke WuHong-Bing JiHong-Xin ShiaYuan-Bin SheYi-Fan Zheng.Fast adsorption of p-nitrophenol from aqueous solution using β-cyclodextrin grafted silica gel[J].Applied Surface Science20153561155-1167.

    [11] 沈海民*,武宏科,纪红兵,史鸿鑫*. β-环糊精-Fe3O4超分子体系的构筑及其应用研究进展[J].有机化学,201434(4)630-646.

    [10] 沈海民*,纪红兵,武宏科,史鸿鑫*.β-环糊精的固载及其应用最新研究进展[J].有机化学,201434(8)1549-1572.

    [9] Hai-Min ShenHong-Bing Ji*. Cyclodextrine-[RuCl2(Arene)]2 conjugates: another  way to enhancethe enantioselectivity of aromatic ketones reduction by aromatic ligands’ volume[J].Tetrahedron201369(39)8360-8367.

    [8] Hai-Min ShenHong-Bing Ji*.Amino alcohol-modified β-cyclodextrin inducing biomimetic asymmetric oxidation of thioanisole in water[J].Carbohydrate Research201235449-58.

    [7] 沈海民,纪红兵*.环糊精衍生物在金属催化有机合成中的应用[J].有机化学,201232(6)975-985.

    [6] Hai-Min ShenHong-Bing Ji*.Biomimetic asymmetric aldol reactions catalyzed by proline derivatives attached to β-cyclodextrin in water[J].Tetrahedron Letters201253(28)3541-3545.

    [5] 沈海民,纪红兵*. β-环糊精衍生物诱导Na2MoO4催化H2O2不对称氧化苯甲硫醚[J].有机化学,201232(9)1684-1689.

    [4] 沈海民,纪红兵*.环糊精衍生物在液相有机合成中的应用[J].有机化学,201131(6)791-803.

    [3] 沈海民,史鸿鑫*,武宏科,项菊萍,朱春凤.N-(p-全氟壬烯氧基苯磺酰基)肌氨酸钠的合成与表面活性[J]. 高校化学工程学报,200923(4)679-683.

    [2] 沈海民,史鸿鑫*,项菊萍,刘秋平,朱春凤.硫酸酯型氟表面活性剂的合成与表面活性[J].应用化学,200926(9)1036-1039.

    [1] 沈海民,史鸿鑫*,武宏科,项菊萍.对全氟壬烯氧基苯磺酸钠的合成与表面活性[J].农药,200746(8)520-522.


    授权专利:

    [12] 沈海民,张羽,孙静. 一种双金属中心金属卟啉及其制备方法和应用[P]. 申请号:202010884408.5, 申请日:2020.08.28. 申请公布号:CN112090449A, 申请公布日:2020.12.18. 授权公告号:CN112090449B,专利号:ZL 202010884408.5,授权公告日:2023.03.31. 申请人:浙江工业大学.

    [11] 沈海民,黄浩. 一种三金属中心(Co&Cu&Zn)2DMOFs/紫外光催化氧化环烷烃的方法[P]. 申请号:202111006432.X, 申请日:2021.08.30. 申请公布号:CN113603564A, 申请公布日:2021.11.05. 授权公告号:CN113603564B,专利号:ZL 202111006432.X,授权公告日:2023.03.14. 申请人:浙江工业大学.

    [10] 沈海民,黄浩. 一种金属卟啉三金属中心2DMOFs及其制备方法和应用[P]. 申请号:202111008838.1, 申请日:2021.08.31. 申请公布号:CN113683619A, 申请公布日:2021.11.23. 授权公告号:CN113683619B,专利号:ZL 202111008838.1,授权公告日:2023.07.14. 申请人:浙江工业大学.

    [9] Hai-Min Shen, Lei Ning, Yuan-Bin She. Confined Porphyrin Co(II) and Preparation Method and Application Thereof [P].  Patent No.: US11420991(B2), Date of Patent: 2022-08-23. Applicant: Zhejiang University of Technology.

    [8]  沈海民,任文山一种Cu(II)/硝酸二元催化体系催化O2氧化环己烯一步合成己二酸的方法[P]. 申请号:2021109811098, 申请日:2021.08.25. 申请公布号:CN113563176A, 申请公布日:2021.10.29. 专利号:ZL 2021109811098授权公告号:CN113563176B授权公告日:2022.12.20. 申请人:浙江工业大学.

    [7]  沈海民,丛淑贞封端3D(II)卟啉POF材料及其制备方法和应用[P]. 申请号:2021109875009, 申请日:2021.08.26. 申请公布号:CN113717394A, 申请公布日:2021.11.30. 专利号: 2021109875009. 授权公告号:CN113717394B,授权公告日:2022.06.03. 申请人:浙江工业大学.

    [6]  沈海民,宁磊,佘远斌一种限域性卟啉Co(II)及其制备方法和应用[P]. 申请号:2019111619249, 申请日:2019.11.25. 申请公布号:CN110938078A, 申请公布日:2020.03.31. 专利号: 2019111619249. 授权公告号:CN110938078B,授权公告日:2021.01.01. 申请人:浙江工业大学.

    [5]  沈海民,齐备,佘远斌甲苯类化合物选择性氧化的方法[P]. 申请号:2019108011331, 申请日:2019.08.28. 申请公布号:CN110563590A, 申请公布日:2019.12.13. 专利号: 2019108011331. 授权公告号:CN110563590B,授权公告日:2022.03.18. 申请人:浙江工业大学.

    [4]  沈海民叶宏亮佘远斌一种乙苯及其衍生物选择性氧化制备苯乙酮及其衍生物的方法[P]. 申请号:2019107949087, 申请日:2019.08.27. 申请公布号:CN110498745A, 申请公布日:2019.11.26. 专利号: 2019107949087. 授权公告号:CN110498745B,授权公告日:2022.06.17. 申请人:浙江工业大学.

    [3]  沈海民史鸿鑫武宏科一种不锈钢氧化层清洗剂及其制备方法和应用[P]. 申请号:2014100424102, 申请日:2014.01.28. 申请公布号:CN103820797A, 申请公布日: 2014.05.28. 申请人:浙江工业大学授权专利号: 2014100424102, 授权公告号: CN103820797B, 授权日: 2016.05.18.

    [2]  佘远斌刘磊沈海民一种乙苯类化合物选择性氧化的方法[P]. 申请号:2019108011346, 申请日:2019.08.28. 申请公布号:CN110483222A, 申请公布日:2019.11.22. 专利号: 2019108011346. 授权公告号:CN110483222B,授权公告日:2022.06.21. 申请人:浙江工业大学.

    [1]  佘远斌胡梦云沈海民一种异丙苯类化合物选择性氧化的方法[P]. 申请号:2019108011327, 申请日:2019.08.28. 申请公布号:CN110423185A, 申请公布日:2019.11.08. 专利号: 2019108011327. 授权公告号:CN110423185B,授权公告日:2022.03.18. 申请人:浙江工业大学.







  • 教学与课程

    1.  主讲本科生专业必修课程,《化工安全与环境》

    2.  主讲本科生专业必修课程,《绿色化工技术》

    3.  主讲本科生专业选修课程,《化工设计B

    4.  辅讲本科生专业必修课程,《化工安全与环境》

    5.  辅讲本科生专业必修课程,《绿色化学原理与应用》

    6.  担任绿色化学教研室主任


  • 育人成果

    1. 2013-2014年,浙江工业大学校优秀班主任

    2. 2015年,指导学生获第七届浙江省大学生化学竞赛一等奖

    3.  2015年,浙江工业大学优秀教师

    4.  2016年,指导硕士研究生周文杰,获优秀研究生国家奖学金

    5.  2020年,指导硕士研究生王雄,获优秀研究生国家奖学金

    6.  2021年,指导硕士研究生吕东,获优秀研究生国家奖学金

    7.  2022年,浙江工业大学优秀本科毕业论文指导教师

    8.  2023年,浙江工业大学优秀本科毕业论文指导教师

  • 科研项目

    1.  环糊精-Fe3O4超分子仿生催化体系的构筑及其对水相不对称反应的调控,国家自然科学基金青年基金项目,2013.01.01 -2016.12.31,主持

    2.  双金属卟啉协同催化氧气选择性氧化环烷烃合成醇、酮研究,国家自然科学基金面上项目,2019.01.01-2022.12.31,主持

    3.  限域环境中双金属中心接力催化O2选择氧化烃类C-H键规律的研究,国家自然科学基金面上项目,2022.01.01- 2025.12.31,主持

    4.  一种防晒剂A二钠盐合成工艺的开发,企业横向课题,75.0万,主持

    5.  无水家用机洗洗衣液配方的研究和开发,企业横向课题,5.0万,主持

    6.  关键医药中间体的工艺研发,企业横向课题,100.0万,主持

    7.  电化铝烫印箔水溶性色料配方开发和涂布工艺改进,企业横向课题,10.0万,主持


  • 科研成果

    学术论文:

    [41] Jia-Ye Ni, Yan-Bo Ding, Jing Sun, Hong-Ke Wu, Hai-Min Shen*, Yuan-Bin She*. Cycloalkanes oxidation with O2 catalyzed by a novel metalloporphyrin -based covalent coupling structure with bimetallic catalytic centers through synergistic mode [J]. Catalysis Communications, 2024, 187: 106876.

    [40] Yu Zhang, Xiao-Ling Feng, Jia-Ye Ni, Bo Fu, Hai-Min Shen*, Yuan-Bin She*. Efficient Inhibition of Deep Conversion of Partial Oxidation Products in C-H Bonds′ Functionalization Utilizing O2 via Relay Catalysis of Dual Metalloporphyrins on Surface of Hybrid Silica Possessing Capacity for Product Exclusion [J]. Biomimetics, 2024, 9: 272.

    [39] Yuan-Bin She, Yu Zhang, Jia-Ye Ni, Xin-Yan Zhou, Hong-Liang Ye, Hai-Min Shen*. Practical and efficient oxygenation of benzylic C-H bonds with dioxygen catalyzed by two-dimensional porous organic frameworks possessing porphyrin cobalt(II) units [J]. Chemical Engineering Science, 2024, 293: 120056.

    [38] Yu Zhang, Bo Fu, Jing Sun, Yan-Bo Ding, Hai-Min Shen*, Yuan-Bin She*. Relay catalysis on the surface of hybrid silica functionalized with dual metalloporphyrins(Co&Zn) for efficient and selective oxygenation of cycloalkanes using oxygen [J]. Molecular Catalysis, 2024, 557: 113957.

    [37] Xin-Yan Zhou, Bo Fu, Wen-Dong Jin, Xiong Wang, Ke-Ke Wang , Mei Wang, Yuan-Bin She, Hai-Min Shen*. Efficient and Selective Oxygenation of Cycloalkanes and Alkyl Aromatics with Oxygen through Synergistic Catalysis of Bimetallic Active Centers in Two-Dimensional Metal-Organic Frameworks Based on Metalloporphyrins [J]. Biomimetics, 2023, 8(3): 325.

    [36] Jia-Ye Ni, Bin He, Hao Huang, Lei Ning, Qiu-Ping Liu, Ke-Ke Wang, Hong-Ke Wu, Hai-Min Shen*, Yuan-Bin She*. Cycloalkanes oxidation with O2 in high-efficiency and high-selectivity catalyzed by 3D MOFs with limiting domain and Zn(AcO)2 through synergistic mode [J]. Molecular Catalysis, 2023, 540: 113027.

    [35] Xin-Yan Zhou, Bin He, Yu Zhang, Jia-Ye Ni, Qiu-Ping Liu, Mei Wang, Hai-Min Shen*, Yuan-Bin She*. Selective and Efficient Catalytic Oxygenation of Alkyl Aromatics Employing H2O2 Catalyzed by Simple Porphyrin Iron(II) under Mild Conditions [J]. Processes, 2023, 11: 1187.

    [34] Hai-Min Shen, Hong-Liang Ye, Jia-Ye Ni, Ke-Ke Wang, Xin-Yan Zhou, Yuan-Bin She*. Oxidation of α-C-H bonds in alkyl aromatics with O2 catalyzed by highly dispersed cobalt(II) coordinated in confined reaction channel of porphyrin-based POFs with simultaneously enhanced conversion and selectivity [J]. Chemical Engineering Science, 2023, 270: 118472.

    [33] A-Bing Guo, Jia-Wei Qin, Ke-Ke Wang, Qiu-Ping Liu, Hong-Ke Wu, Mei Wang, Hai-Min Shen*, Yuan-Bin She. Synergetic catalytic oxidation of C-H bonds in cycloalkanes and alkyl aromatics by dimetallic active sites in 3D metalloporphyrinic MOFs employing O2 as oxidant with increased conversion and unconsumed selectivity [J]. Molecular Catalysis, 2023, 535:112853.

    [32] Hai-Min Shen, Xiong Wang, Hao Huang, Qiu-Ping Liu, Dong Lv, Yuan-Bin She*. Staged oxidation of hydrocarbons with simultaneously enhanced conversion and selectivity employing O2 as oxygen source catalyzed by 2D metalloporphyrin-based MOFs possessing bimetallic active centers [J]. Chemical Engineering Journal, 2022, 443: 136126.

    [31] Hai-Min Shen, A-Bing Guo, Yu Zhang, Qiu-Ping Liu, Jia-Wei Qin, Yuan-Bin She*. Relay catalysis of hydrocarbon oxidation using O2 in the confining domain of 3D metalloporphyrin-based metal-organic frameworks with bimetallic catalytic centers [J]. Chemical Engineering Science, 2022, 260: 117825.

    [30] Jia-Ye Ni, Shu-Zhen Cong, Lei Ning, Mei Wang, Hai-Min Shen*, Yuan-Bin She*. Binary catalytic systems constructed by porphyrin cobalts(II) with confining nano-region and Zn(OAc)2 for oxygenation of cycloalkanes with O2 in relay mode [J]. Molecular Catalysis, 2022, 531:112676.

    [29] Hai-Min Shen, Xiong Wang, Lei Ning, A-Bing Guo, Jin-Hui Deng, Yuan-Bin She*. Efficient        oxidation of cycloalkanes with simultaneously increased conversion and selectivity using O2 catalyzed by metalloporphyrins and boosted by Zn(AcO)2: A practical strategy to inhibit the formation of aliphatic diacids [J]. Applied Catalysis A, General, 2021, 609: 117904.

    [28] Hai-Min Shen, Hong-Liang Ye, Qin Wang, Meng-Yun Hu, Lei Liu, Yuan-Bing She*. Efficient oxidation of cumene to cumene hydroperoxide with ambient O2 catalyzed by metalloporphyrins [J]. Journal of Porphyrins and Phthalocyanines, 2021, 25: 314-322.

    [27] Hai-Min Shen, Meng-Yun Hu, Lei Liu, Bei Qi, Hong-Liang Ye, Yuan-Bin She*. Efficient and selective oxidation of tertiary benzylic C-H bonds with Ocatalyzed by metalloporphyrins under mild and solvent-free conditions [J]. Applied Catalysis A, General, 2020, 599: 117599.

    [26] Hai-Min Shen, Bei Qi, MengYun Hu, Lei Liu, HongLiang Ye, YuanBin She*. Selective Solvent-Free and Additive-Free Oxidation of Primary Benzylic C-H Bonds with O2 Catalyzed by the Combination of Metalloporphyrin with NHydroxyphthalimide [J]. Catalysis Letters, 2020, 150: 3096-3111.

    [25] Hai-Min Shen*, Lei Liu, Bei Qi, Meng-Yun Hu, Hong-Liang Ye, Yuan-Bin She. Efficient and selective oxidation of secondary benzylic C-H bonds to ketones with O2 catalyzed by metalloporphyrins under solvent-free and additive-free conditions [J]. Molecular Catalysis, 2020, 493: 111102.

    [24] Hai-Min Shen, Xiong Wang, A-Bing Guo, Long Zhang, Yuan-Bing She*. Catalytic oxidation of cycloalkanes by porphyrin cobalt(II) through efficient utilization of oxidation intermediates [J]. Journal of Porphyrins and Phthalocyanines, 2020, 24: 1166-1173.

    [23] Hai-Min Shen, Long Zhang, Jin-Hui Deng, Jing Sun, Yuan-Bin She*. Enhanced catalytic performance of porphyrin cobalt(II) in the solvent-free oxidation of cycloalkanes (C5~C8) with molecular oxygen promoted by porphyrin zinc(II) [J]. Catalysis Communications, 2019, 132: 105809 .

    [22] Hai-Min Shen, Yan Wang, Jin-Hui Deng, Long Zhang, Yuan-Bin She*. Catalyst-free and solvent-free oxidation of cycloalkanes (C5-C8) with molecular oxygen: Determination of autoxidation temperature and product distribution[J]. Chinese Journal of Chemical Engineerin201826(5)1064-1070.

    [21] 佘远斌,邓金辉,张龙,沈海民*. 氧气催化氧化环己烷[J].化学进展,201830(1)124-136.

    [20] 沈海民,王岩,佘远斌*.金属卟啉催化氧化环己烷最新研究进展[J].化工进展,201837(6)2031-2045.

    [19] 韩叶强,周文杰,沈海民*,刘秋平,于文艳,纪红兵,佘远斌*.固载化β-环糊精吸附环境污染物的研究进展[J].有机化学,201636(2)248-257.

    [18] Hai-Min Shen*Wen-Jie ZhouWu-Bin YuHong-Ke WuQiu-Ping LiuHong-Bing JiYan WangYuan-Bin She*.Metal-free chemoselective oxidation of sulfides to sulfoxides catalyzed by immobilized L-aspartic acid and L-glutamic acid in an aqueous phase at room temperature[J].New Journal of Chemistry201640(6)4874-4878.

    [17] 沈海民*,武宏科,史鸿鑫,纪红兵,余武斌*.非均相环糊精在水相有机合成反应中的应用[J].化学进展,201527(1)70-78.

    [16] 沈海民*,方红果,武宏科,纪红兵,史鸿鑫*.环糊精衍生物的分子形态及其构筑策略研究进展[J].化工进展,201534(2)430-446.

    [15] Hai-Min Shen*Wen-Jie ZhouHong-Ke WuWu-Bin YuNing AiHong-Bing JiHong-Xin ShiYuan-Bin She*.Metal-free chemoselective oxidation of sulfides to sulfoxides catalyzed by immobilized taurine and homotaurine in aqueous phase at room temperature[J].Tetrahedron Letters201556(30)4494-4498.

    [14] Hai-Min Shen*Wen-Jie ZhouXin MaHong-Ke WuWu-Bin YuNing AiHong-Bing JiHong-Xin Shi Yuan-Bin She*.pH-Dependence of the Aqueous Phase Room Temperature Brønsted Acid-Catalyzed Chemoselective Oxidation of Sulfides with H2O2[J].Molecules201520(9)16709-16722.

    [13] Hai-Min ShenGong-Yuan ZhuWu-Bin YuHong-Ke WuHong-Bing Ji   Hong-Xin ShiYi-Fan Zheng*Yuan-Bin She*.Surface immobilization of β-cyclodextrin on hybrid silica and its fast adsorption performance of p-nitrophenol from the aqueous phase[J].RSC Advances20155(103)84410-84422. 

    [12] Hai-Min Shen*Gong-Yuan ZhuWu-Bin YuHong-Ke WuHong-Bing JiHong-Xin ShiaYuan-Bin SheYi-Fan Zheng.Fast adsorption of p-nitrophenol from aqueous solution using β-cyclodextrin grafted silica gel[J].Applied Surface Science20153561155-1167.

    [11] 沈海民*,武宏科,纪红兵,史鸿鑫*. β-环糊精-Fe3O4超分子体系的构筑及其应用研究进展[J].有机化学,201434(4)630-646.

    [10] 沈海民*,纪红兵,武宏科,史鸿鑫*.β-环糊精的固载及其应用最新研究进展[J].有机化学,201434(8)1549-1572.

    [9] Hai-Min ShenHong-Bing Ji*. Cyclodextrine-[RuCl2(Arene)]2 conjugates: another  way to enhancethe enantioselectivity of aromatic ketones reduction by aromatic ligands’ volume[J].Tetrahedron201369(39)8360-8367.

    [8] Hai-Min ShenHong-Bing Ji*.Amino alcohol-modified β-cyclodextrin inducing biomimetic asymmetric oxidation of thioanisole in water[J].Carbohydrate Research201235449-58.

    [7] 沈海民,纪红兵*.环糊精衍生物在金属催化有机合成中的应用[J].有机化学,201232(6)975-985.

    [6] Hai-Min ShenHong-Bing Ji*.Biomimetic asymmetric aldol reactions catalyzed by proline derivatives attached to β-cyclodextrin in water[J].Tetrahedron Letters201253(28)3541-3545.

    [5] 沈海民,纪红兵*. β-环糊精衍生物诱导Na2MoO4催化H2O2不对称氧化苯甲硫醚[J].有机化学,201232(9)1684-1689.

    [4] 沈海民,纪红兵*.环糊精衍生物在液相有机合成中的应用[J].有机化学,201131(6)791-803.

    [3] 沈海民,史鸿鑫*,武宏科,项菊萍,朱春凤.N-(p-全氟壬烯氧基苯磺酰基)肌氨酸钠的合成与表面活性[J]. 高校化学工程学报,200923(4)679-683.

    [2] 沈海民,史鸿鑫*,项菊萍,刘秋平,朱春凤.硫酸酯型氟表面活性剂的合成与表面活性[J].应用化学,200926(9)1036-1039.

    [1] 沈海民,史鸿鑫*,武宏科,项菊萍.对全氟壬烯氧基苯磺酸钠的合成与表面活性[J].农药,200746(8)520-522.


    授权专利:

    [12] 沈海民,张羽,孙静一种双金属中心金属卟啉及其制备方法和应用[P]. 申请号:202010884408.5, 申请日:2020.08.28. 申请公布号:CN112090449A, 申请公布日:2020.12.18. 授权公告号:CN112090449B,专利号:ZL 202010884408.5,授权公告日:2023.03.31. 申请人:浙江工业大学.

    [11] 沈海民,黄浩一种三金属中心(Co&Cu&Zn)2DMOFs/紫外光催化氧化环烷烃的方法[P]. 申请号:202111006432.X, 申请日:2021.08.30. 申请公布号:CN113603564A, 申请公布日:2021.11.05. 授权公告号:CN113603564B,专利号:ZL 202111006432.X,授权公告日:2023.03.14. 申请人:浙江工业大学.

    [10] 沈海民,黄浩一种金属卟啉三金属中心2DMOFs及其制备方法和应用[P]. 申请号:202111008838.1, 申请日:2021.08.31. 申请公布号:CN113683619A, 申请公布日:2021.11.23. 授权公告号:CN113683619B,专利号:ZL 202111008838.1,授权公告日:2023.07.14. 申请人:浙江工业大学.

    [9] Hai-Min Shen, Lei Ning, Yuan-Bin She. Confined Porphyrin Co(II) and Preparation Method and Application Thereof [P].  Patent No.: US11420991(B2), Date of Patent: 2022-08-23. Applicant: Zhejiang University of Technology.

    [8]  沈海民,任文山一种Cu(II)/硝酸二元催化体系催化O2氧化环己烯一步合成己二酸的方法[P]. 申请号:2021109811098, 申请日:2021.08.25. 申请公布号:CN113563176A, 申请公布日:2021.10.29. 专利号:ZL 2021109811098,授权公告号:CN113563176B,授权公告日:2022.12.20. 申请人:浙江工业大学.

    [7]  沈海民,丛淑贞封端3D(II)卟啉POF材料及其制备方法和应用[P]. 申请号:2021109875009, 申请日:2021.08.26. 申请公布号:CN113717394A, 申请公布日:2021.11.30. 专利号: 2021109875009. 授权公告号:CN113717394B,授权公告日:2022.06.03. 申请人:浙江工业大学.

    [6]  沈海民,宁磊,佘远斌一种限域性卟啉Co(II)及其制备方法和应用[P]. 申请号:2019111619249, 申请日:2019.11.25. 申请公布号:CN110938078A, 申请公布日:2020.03.31. 专利号: 2019111619249. 授权公告号:CN110938078B,授权公告日:2021.01.01. 申请人:浙江工业大学.

    [5]  沈海民,齐备,佘远斌甲苯类化合物选择性氧化的方法[P]. 申请号:2019108011331, 申请日:2019.08.28. 申请公布号:CN110563590A, 申请公布日:2019.12.13. 专利号: 2019108011331. 授权公告号:CN110563590B,授权公告日:2022.03.18. 申请人:浙江工业大学.

    [4]  沈海民叶宏亮佘远斌一种乙苯及其衍生物选择性氧化制备苯乙酮及其衍生物的方法[P]. 申请号:2019107949087, 申请日:2019.08.27. 申请公布号:CN110498745A, 申请公布日:2019.11.26. 专利号: 2019107949087. 授权公告号:CN110498745B,授权公告日:2022.06.17. 申请人:浙江工业大学.

    [3]  沈海民史鸿鑫武宏科一种不锈钢氧化层清洗剂及其制备方法和应用[P]. 申请号:2014100424102, 申请日:2014.01.28. 申请公布号:CN103820797A, 申请公布日: 2014.05.28. 申请人:浙江工业大学授权专利号: 2014100424102, 授权公告号: CN103820797B, 授权日: 2016.05.18.

    [2]  佘远斌刘磊沈海民一种乙苯类化合物选择性氧化的方法[P]. 申请号:2019108011346, 申请日:2019.08.28. 申请公布号:CN110483222A, 申请公布日:2019.11.22. 专利号: 2019108011346. 授权公告号:CN110483222B,授权公告日:2022.06.21. 申请人:浙江工业大学.

    [1]  佘远斌胡梦云沈海民一种异丙苯类化合物选择性氧化的方法[P]. 申请号:2019108011327, 申请日:2019.08.28. 申请公布号:CN110423185A, 申请公布日:2019.11.08. 专利号: 2019108011327. 授权公告号:CN110423185B,授权公告日:2022.03.18. 申请人:浙江工业大学.


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